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Phenolphthalein
Danger
GHS08
NOAEL Data
IARC Group 2B
SVHC
Prop 65
REACH Registered
Cosmetic Ingredient
Phenolphthalein
Also known as: 3,3-Bis(4-hydroxyphenyl)-2-benzofuran-1(3H)-one, 5-18-04-00188, BRN 0284423, Correctol, alpha-Di(p-hydroxyphenyl)phthalide (+15 more)
CAS 77-09-8
Phenolphthalein (CAS 77-09-8) is a chemical substance with GHS signal word Danger; key hazard signal: H350; H341; H361f ***. Key regulatory status: SVHC Candidate List, California Proposition 65, REACH registered, 7 regulatory/inventory lists, cosmetic ingredient cross-reference; source data from ECHA CLP, EPA ToxValDB, EPA CPDat, IARC, ECHA REACH, ECHA SVHC, CA Prop 65, EPA TRI.
View cosmetic safety profile for Phenolphthalein →
Cross-Vertical Regulatory Divergence
Phenolphthalein is prohibited in EU cosmetics but has active industrial GHS classifications (H350, H341, H361f).
SOURCE
Cross-vertical comparison
Cosmetics: ingredients.eu_status; Chemicals: eu_clp_annex_vi.signal_word/hazard_statement_code
SOURCE
noael studies public
NOAEL studies
61
SOURCE
chemical inventory jurisdictions
Regulatory lists
7
SOURCE
eu clp annex vi
GHS signal
Danger
Chemical Identity
CAS, identifiers, formula, and alternate names for the matched substance record.
SOURCE
DSSTox identifiers
26 fields
Molecular Formula
C20H14O4
InChI Key
KJFMBFZCATUALV-UHFFFAOYSA-N
Monoisotopic Mass
318.089209
Synonyms
3,3-Bis(4-hydroxyphenyl)-2-benzofuran-1(3H)-one 5-18-04-00188 BRN 0284423 Correctol alpha-Di(p-hydroxyphenyl)phthalide Dihydroxyphthalophenone EINECS 201-004-7 Espotabs Evac-U-Gen Evac-Q-Kit Evac-Q-Kwik Evac-V-Lax
IARC Carcinogen Classification
Carcinogenic hazard classification from IARC monograph evaluations.
SOURCE
IARC Monographs on the Identification of Carcinogenic Hazards to Humans
1 records
Group Meaning Evaluated Volume
Group 2B Possibly carcinogenic 1999 76
Substance of Very High Concern (SVHC)
Candidate List status and reason under the ECHA REACH SVHC program.
SOURCE
ECHA (EU)
1 records
Substance Reason Included
Phenolphthalein Carcinogenic (Article 57a) 19-Dec-2011
California Proposition 65
California OEHHA listing status and toxicity category.
SOURCE
California OEHHA Proposition 65 List
1 records
Chemical Toxicity Type Cancer Developmental Listed
- cancer Yes No -
GHS / CLP Classification
EU harmonized hazard classification, hazard statements, pictograms, and signal word.
SOURCE
EU CLP Annex VI (ECHA)
1 classifications
Hazard Class H-Statements Pictograms Signal
Carc. 1B; Muta. 2; Repr. 2 H350; H341; H361f *** GHS08 Danger
Functional Uses
Industrial and product-use categories associated with this substance.
SOURCE
EPA CPDat
1 records
No specific technical function
Regulatory Lists
Inventory, screening, and regulatory list matches from public chemical databases.
SOURCE
EPA CPDat
7 records
List Keyword Source
banned; Europe; Personal care European Commission CosIng
active_ingredient; Australia Australian Pesticides and Veterinary Medicines Authority CPCat
pharmaceutical US International Trade Commission CPCat
OEHHA Proposition 65 (3/2019) STATE OF CALIFORNIA ENVIRONMENTAL PROTECTION AGENCY OEHHA Proposition 65 List
Canada; pharmaceutical DrugBank DrugBank
Canada; pharmaceutical DrugBank DrugBank
OEHHA Proposition 65 (1/2023) California Office of Environmental Health Hazard Assessment OEHHA Proposition 65 List
NOAEL Studies
Toxicology endpoints rendered from public NOAEL study rows.
SOURCE
NOAEL studies
Showing 50 of 61 studies
Value Unit Endpoint Route Species Source
7.38945042561721 uM AC50 - - NTP_ICE_endocrine
33.6958260508959 uM AC50 - - NTP_ICE_endocrine
5.07312527582202 uM ACC - - NTP_ICE_endocrine
32.4294634408271 uM ACC - - NTP_ICE_endocrine
ABcancer listing type California Proposition 65 listing - - California Proposition 65
ABcancer listing type California Proposition 65 listing - - California Proposition 65
ABcancer listing type California Proposition 65 listing - - California Proposition 65
ABcancer listing type California Proposition 65 listing - - California Proposition 65
41.6 uL/min/10^6 cells Clint - Rat NTP_ICE_adme_parameters
47.4 uL/min/10^6 cells Clint - Human NTP_ICE_adme_parameters
6QK969R2IF UNII FDA UNII substance identifier - - openFDA substances
6QK969R2IF UNII FDA UNII substance identifier - - openFDA substances
6QK969R2IF UNII FDA UNII substance identifier - - openFDA substances
6QK969R2IF UNII FDA UNII substance identifier - - openFDA substances
0.0086 fraction Fu - Rat NTP_ICE_adme_parameters
0.03116 fraction Fu - Human NTP_ICE_adme_parameters
2B IARC group IARC carcinogenicity classification - - IARC Monographs
2 unitless IARC group - - NTP_ICE_cancer
=1 mg/day LEL injection Rat ToxValDB_Uterotrophic_Hershberger_DB
=300 mg/kg bw/day LEL oral Mouse ToxValDB_ToxRefDB
=300 mg/kg bw/day LEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=400 mg/kg bw/day LEL oral Mouse ToxValDB_ToxRefDB
=400 mg/kg bw/day LEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=500 mg/kg bw/day LEL oral Mouse ToxValDB_ToxRefDB
=500 mg/kg bw/day LEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=1700 mg/kg bw/day LEL oral Rat ToxValDB_ToxRefDB
=1700 mg/kg bw/day LEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=2400 mg/kg bw/day LEL oral Mouse ToxValDB_ToxRefDB
=2400 mg/kg bw/day LEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=10500 mg/kg bw/day LEL oral Rat ToxValDB_ToxRefDB
=10500 mg/kg bw/day LEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=11000 mg/kg bw/day LEL oral Rat ToxValDB_ToxRefDB
=11000 mg/kg bw/day LEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=15000 mg/kg bw/day LEL oral Mouse ToxValDB_ToxRefDB
=15000 mg/kg bw/day LEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=2000 mg/kg bw/day LOAEL oral Mouse ToxValDB_ToxRefDB
=2000 mg/kg bw/day LOAEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
- unitless Model Score - - NTP_ICE_endocrine
0.174 unitless Model Score - - NTP_ICE_endocrine
0.276 unitless Model Score - - NTP_ICE_endocrine
>- mg/kg bw/day NEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=400 mg/kg bw/day NEL oral Rat ToxValDB_ToxRefDB
=400 mg/kg bw/day NEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=800 mg/kg bw/day NEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=1200 mg/kg bw/day NEL oral Mouse ToxValDB_ToxRefDB
=1200 mg/kg bw/day NEL oral mouse (b6c3f1; B6C3F1) ToxRefDB_ToxRefDB_v3_pod.csv
=4000 mg/kg bw/day NEL oral Rat ToxValDB_ToxRefDB
=4000 mg/kg bw/day NEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
=4500 mg/kg bw/day NEL oral Rat ToxValDB_ToxRefDB
=4500 mg/kg bw/day NEL oral rat (fischer; Fischer 344) ToxRefDB_ToxRefDB_v3_pod.csv
Showing 50 of 61 studies
REACH Registration
Registration status from the ECHA REACH registered substances database.
SOURCE
ECHA (EU)
1 records
EPA Toxic Release Inventory (TRI)
TRI hazard and reporting flags for the matched chemical.
SOURCE
EPA Toxics Release Inventory (TRI) chemical list
1 records
Chemical Category Flags
Phenolphthalein - -
Cosmetic Safety Profile
Same-CAS cosmetic ingredient record for cross-vertical context.
SOURCE
CosIng / Ingredients DB
Category
Cosmetic Ingredient
View full cosmetic safety profile →
Frequently Asked Questions
What is the GHS hazard classification for Phenolphthalein?
Phenolphthalein (CAS 77-09-8) is classified under EU CLP Annex VI as Carc. 1B; Muta. 2; Repr. 2 with signal word Danger. Hazard statements: H350; H341; H361f ***. Source: EU CLP Annex VI (ECHA).
What is the NOAEL for Phenolphthalein?
Phenolphthalein has 61 NOAEL studies in the database. The lowest reported value is 5.07312527582202 uM. Source: NTP_ICE_endocrine.
What regulatory lists include Phenolphthalein?
Phenolphthalein appears on 6 regulatory/inventory lists including banned; Europe; Personal care, active_ingredient; Australia, pharmaceutical, and 3 more. Source: EPA CPDat.
Is Phenolphthalein a carcinogen according to IARC?
Phenolphthalein is classified by IARC as Group 2B — possibly carcinogenic to humans (evaluated 1999). Source: IARC Monographs on the Identification of Carcinogenic Hazards to Humans.
Is Phenolphthalein on the California Proposition 65 list?
Yes, Phenolphthalein is listed under California Proposition 65 for cancer. Source: California OEHHA Proposition 65.
Is Phenolphthalein a Substance of Very High Concern (SVHC)?
Yes, Phenolphthalein is listed on the ECHA REACH Candidate List as a Substance of Very High Concern. Reason: Carcinogenic (Article 57a). Source: ECHA SVHC Candidate List.
Is Phenolphthalein used in cosmetics?
Yes, Phenolphthalein is also indexed as a cosmetic ingredient under the name Phenolphthalein. View the full cosmetic safety profile on the ingredient page for detailed safety data, SCCS opinions, and regulatory status.
Where does the safety data for Phenolphthalein come from?
Safety data is sourced from ECHA CLP Annex VI, EPA ToxValDB, EPA CPDat, EPA DSSTox, IARC Monographs, ECHA REACH, ECHA SVHC Candidate List, California Proposition 65, EPA Toxics Release Inventory, CosIng / Ingredients DB, ChEMBL / DailyMed. All data traces to primary regulatory sources and is updated from official government databases.
Does Phenolphthalein have different safety status in cosmetics vs industrial chemicals?
Phenolphthalein is prohibited in EU cosmetics but has active industrial GHS classifications (H350, H341, H361f).
Is Phenolphthalein used outside industrial chemicals?
Phenolphthalein also appears in cosmetics, pharmaceutical databases.