What is the GHS hazard classification for Sulfuric acid?
Sulfuric acid (CAS 7664-93-9) is classified under EU CLP Annex VI as Skin Corr. 1A with signal word Danger. Hazard statements: H314. Source: EU CLP Annex VI (ECHA).
Also known as: Battery acid, Caswell No. 815, EINECS 231-639-5, Electrolyte acid, EPA Pesticide Chemical Code 078001 (+12 more)
CAS 7664-93-9
Sulfuric acid (CAS 7664-93-9) is a chemical substance with GHS signal word Danger; key hazard signal: H314. Key regulatory status: REACH registered, 58 regulatory/inventory lists, cosmetic ingredient cross-reference; source data from ECHA CLP, EPA ToxValDB, EPA CPDat, AICIS, ECHA REACH, ILO ICSC, OSHA, EPA TRI.
Sulfuric acid is classified GHS Danger (H314) in the chemicals database but is restricted in EU cosmetics.
CAS, identifiers, formula, and alternate names for the matched substance record.
EU harmonized hazard classification, hazard statements, pictograms, and signal word.
| Hazard Class | H-Statements | Pictograms | Signal |
|---|---|---|---|
| Skin Corr. 1A | H314 | GHS05 | Danger |
International Chemical Safety Card hazard and exposure summary.
| Field | Value |
|---|---|
| GHS Signal Word | DANGER |
| GHS Hazard Statements | Fatal if inhaled Causes severe skin burns and eye damage May cause respiratory irritation May be osive to metals See Notes |
| Short-term Effects | The substance is very corrosive to the eyes, skin and respiratory tract. Corrosive on ingestion. Exposure could cause asphyxiation due to swelling in the throat. Inhalation of high concentrations may cause lung oedema, but only after initial corrosive effects on the eyes and the upper respiratory tract have become manifest. Inhalation may cause asthma-like reactions (RADS). Medical observation is indicated. See Notes. |
| Long-term Effects | Repeated or prolonged contact with skin may cause dermatitis. Repeated or prolonged inhalation may cause effects on the lungs. Risk of tooth erosion upon repeated or prolongated exposure to an aerosol of this substance. Mists of this strong inorganic acid are carcinogenic to humans. See Notes. |
| Routes of Exposure | Serious local effects by all routes of exposure. The substance can be absorbed into the body by inhalation of its aerosol. |
Occupational exposure limits from OSHA, NIOSH, and ACGIH rows.
| Agency | Metric | Value | ppm | mg/m3 | Skin |
|---|---|---|---|---|---|
| OSHA | TWA | 1 mg/m³ | - | 1 | N |
| NIOSH | TWA | 1 mg/m³ | - | 1 | N |
| ACGIH | TWA | 0.2 mg/m³ (thoracic particulate matter) [2000] | - | 0.2 | N |
| CAL/OSHA | TWA | 0.1 mg/m³ | - | 0.1 | N |
| CAL/OSHA | STEL | 3 mg/m³ | - | 3 | N |
| NIOSH | IDLH | 15 mg/m³ | - | 15 | - |
Industrial and product-use categories associated with this substance.
Inventory, screening, and regulatory list matches from public chemical databases.
| List | Keyword | Source |
|---|---|---|
| pharmaceutical | US International Trade Commission | CPCat |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | State of California | State of California |
| active_ingredient; Pesticides | California Department of Pesticide Regulation | State of California |
| inert_ingredient; Pesticides | EPA | CPCat |
| inert_ingredient; non_food_use; Pesticides | EPA | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; Pesticides | MN Department of Agriculture Pesticide Sales Database | CPCat |
| active_ingredient; agricultural; applied; fruits_and_vegetables; Pesticides | USDA | United States Department of Agriculture (USDA) |
| active_ingredient; agricultural; Pesticides | USDA | United States Department of Agriculture (USDA) |
| active_ingredient; agricultural; applied; fruits_and_vegetables; Pesticides | USDA | United States Department of Agriculture (USDA) |
| active_ingredient; agricultural; Pesticides | USDA | United States Department of Agriculture (USDA) |
| active_ingredient; agricultural; applied; fruits_and_vegetables; Pesticides | USDA | United States Department of Agriculture (USDA) |
| active_ingredient; agricultural; Pesticides | USDA | United States Department of Agriculture (USDA) |
Toxicology endpoints rendered from public NOAEL study rows.
| Value | Unit | Endpoint | Route | Species | Source |
|---|---|---|---|---|---|
| 1.5 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 9.09 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 14.98 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 15 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 16.15 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 16.86 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| 22.63 | min | Breakthrough Time | Dermal | - | NTP_ICE_skin_irritation |
| O40UQP6WCF | UNII | FDA UNII substance identifier | - | - | openFDA substances |
| O40UQP6WCF | UNII | FDA UNII substance identifier | - | - | openFDA substances |
| O40UQP6WCF | UNII | FDA UNII substance identifier | - | - | openFDA substances |
| O40UQP6WCF | UNII | FDA UNII substance identifier | - | - | openFDA substances |
| 1 | unitless | GHS Classification | Ocular | Rabbit | NTP_ICE_eye_irritation |
| 1 | unitless | GHS classification | Dermal | Rabbit | NTP_ICE_skin_irritation |
| 0.375 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| 0.425 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| 0.51 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| 1.391 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| 1.6836 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| 3.6 | mg/L | LC50 | Inhalation | - | NTP_ICE_acute_inhalation |
| =5 | mg/m3 | LEL | inhalation | Human | ToxValDB_NIOSH_IDLH |
| =0.38 | mg/m3 | LOAEL | inhalation | Monkey | ToxValDB_Cal_OEHHA_REL_derivations |
| =0.45 | mg/m3 | NOAEL | inhalation | Human | ToxValDB_Cal_OEHHA_REL_derivations |
| 214 | mg/kg bw/day | NOAEL | oral | rat | COSMOS_DB |
| 266 | mg/kg bw/day | NOAEL | oral | sheep | COSMOS_DB |
| 1429 | mg/kg bw/day | NOAEL | oral | mouse | COSMOS_DB |
| =0.001 | mg/m3 | RfC | inhalation | Human | ToxValDB_RSL |
| 0.5 | kiloohms | TER | Dermal | - | NTP_ICE_skin_irritation |
| 0.6 | kiloohms | TER | Dermal | - | NTP_ICE_skin_irritation |
| 0.8 | kiloohms | TER | Dermal | - | NTP_ICE_skin_irritation |
| 0.5 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 0.6 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 0.8 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 1.7 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 2 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 2.3 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 2.6 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 3.3 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 3.7 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 4.1 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 4.5 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 4.7 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 4.9 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 5.5 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 5.7 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 9.7 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 10.1 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 11.3 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 14.4 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 17.6 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
| 47.4 | % | Viability (240 minutes) | Dermal | - | NTP_ICE_skin_irritation |
Showing 50 of 100 studies
Registration status from the ECHA REACH registered substances database.
| Status | Name | EC Number | Link |
|---|---|---|---|
| Registered | Sulphuric acid | 231-639-5 | ECHA overview → |
TRI hazard and reporting flags for the matched chemical.
| Chemical | Category | Flags |
|---|---|---|
| Sulfuric acid (acid aerosols) | - | - |
Australian industrial chemicals inventory status and applicable conditions.
Same-CAS cosmetic ingredient record for cross-vertical context.
Same-CAS pharmaceutical records from drug and bioactivity sources.
Same-CAS food additive, ADI, and GRAS records where available.
E513 — 1 food-safety record found.
View full food safety profile →Same-CAS cannabis compliance and lab records where available.
1 cannabis record found in efsa substances.
View full cannabis profile →Sulfuric acid (CAS 7664-93-9) is classified under EU CLP Annex VI as Skin Corr. 1A with signal word Danger. Hazard statements: H314. Source: EU CLP Annex VI (ECHA).
Sulfuric acid has 100 NOAEL studies in the database. The lowest reported value is 0.001 mg/m3 via inhalation in Human. Source: ToxValDB_RSL.
Sulfuric acid appears on 12 regulatory/inventory lists including pharmaceutical, active_ingredient; Pesticides, inert_ingredient; Pesticides, and 9 more. Source: EPA CPDat.
Occupational exposure limits for Sulfuric acid are set by OSHA, NIOSH, ACGIH. 6 limit values from official agencies are documented in the database. Source: OSHA, NIOSH, ACGIH.
Yes, Sulfuric acid is also indexed as a cosmetic ingredient under the name Sulfuric Acid. View the full cosmetic safety profile on the ingredient page for detailed safety data, SCCS opinions, and regulatory status.
Safety data is sourced from ECHA CLP Annex VI, EPA ToxValDB, EPA CPDat, AICIS (Australian Industrial Chemicals Introduction Scheme), EPA DSSTox, ECHA REACH, ILO/WHO ICSC, OSHA/NIOSH/ACGIH, EPA Toxics Release Inventory, CosIng / Ingredients DB, ChEMBL / DailyMed, EFSA / FDA GRAS, cannabis regulatory/lab databases. All data traces to primary regulatory sources and is updated from official government databases.
Sulfuric acid is classified GHS Danger (H314) in the chemicals database but is restricted in EU cosmetics.
Sulfuric acid also appears in cosmetics, pharmaceutical, food safety, cannabis databases.