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2-Methyl-2,4-pentanediol
Warning
GHS07
NOAEL Data
REACH Registered
Cosmetic Ingredient
2-Methyl-2,4-pentanediol
Also known as: Hexylene glycol, 4-01-00-02565, BRN 1098298, Caswell No. 574, EINECS 203-489-0 (+12 more)
CAS 107-41-5
2-Methyl-2,4-pentanediol (CAS 107-41-5) is a chemical substance with GHS signal word Warning; key hazard signal: H315; H319. Key regulatory status: REACH registered, 20 regulatory/inventory lists, cosmetic ingredient cross-reference; source data from ECHA CLP, EPA ToxValDB, EPA CPDat, AICIS, ECHA REACH, ILO ICSC, OSHA.
View cosmetic safety profile for Hexylene Glycol →
SOURCE
noael studies public
NOAEL studies
28
SOURCE
chemical inventory jurisdictions
Regulatory lists
20
SOURCE
eu clp annex vi
GHS signal
Warning
Chemical Identity
CAS, identifiers, formula, and alternate names for the matched substance record.
SOURCE
DSSTox identifiers
23 fields
Name
2-Methyl-2,4-pentanediol
InChI Key
SVTBMSDMJJWYQN-UHFFFAOYSA-N
Monoisotopic Mass
118.09938
Synonyms
Hexylene glycol 4-01-00-02565 BRN 1098298 Caswell No. 574 EINECS 203-489-0 EPA Pesticide Chemical Code 068601 Pinakon (+-)-2-Methyl-2,4-pentanediol UNII-KEH0A3F75J 1,1,3-trimethyl-1,3-propanediol 1,3,3-trimethyl-1,3-propanediol 1,3-dimethyl-3-hydroxybutanol
GHS / CLP Classification
EU harmonized hazard classification, hazard statements, pictograms, and signal word.
SOURCE
EU CLP Annex VI (ECHA)
1 classifications
Hazard Class H-Statements Pictograms Signal
Skin Irrit. 2; Eye Irrit. 2 H315; H319 GHS07 Warning
ICSC Chemical Safety
International Chemical Safety Card hazard and exposure summary.
SOURCE
ILO/WHO International Chemical Safety Cards
1 records
Field Value
Short-term Effects The substance is irritating to the eyes, skin and respiratory tract.
Long-term Effects Repeated or prolonged contact with skin may cause dermatitis.
Routes of Exposure The substance can be absorbed into the body by inhalation of its aerosol.
OSHA Exposure Limits
Occupational exposure limits from OSHA, NIOSH, and ACGIH rows.
SOURCE
OSHA / NIOSH / ACGIH occupational exposure limits
4 records
Agency Metric Value ppm mg/m3 Skin
NIOSH CEILING 25 ppm (125 mg/m³) 25 125 N
ACGIH TWA 25 ppm (vapor fraction) [2016] 25 - N
ACGIH STEL 50 ppm (vapor fraction), 10 mg/mg³ (inhalable particulate matter, aerosol only) [2016] 50 10 N
CAL/OSHA CEILING 25 ppm (125 mg/m³) 25 125 N
Functional Uses
Industrial and product-use categories associated with this substance.
SOURCE
EPA CPDat
60 records
Solvent Surfactant (surface active agent) Softener and conditioner Emulsifier Fragrance Viscosity modifier Filler Plasticizer Chelating agent Anti-adhesive/cohesive Wetting agent (non-aqueous) Solubility enhancer
Regulatory Lists
Inventory, screening, and regulatory list matches from public chemical databases.
SOURCE
EPA CPDat
20 records
List Keyword Source
Europe; Specialty occupational products Danish Environmental Protection Agency Danish EPA
IFRA Transparency IFRA IFRA
SCIL (9/2019) USEPA Safer Chemical Ingredients List
consumer_product; Europe Danish Environmental Protection Agency Danish EPA
consumer_product; detected; Europe Danish Environmental Protection Agency Danish EPA
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides State of California State of California
active_ingredient; Pesticides California Department of Pesticide Regulation State of California
inert_ingredient; non_food_use; Pesticides EPA CPCat
Arts and crafts/Office supplies - home office - pens and markers; detected; Europe Danish Environmental Protection Agency Danish EPA
Indirect additives food contact (10/2018) FDA United States Food and Drug Administration (FDA)
children; Europe; Personal care Danish Environmental Protection Agency Danish EPA
children; Europe; Personal care - hair styling and care - shampoo Danish Environmental Protection Agency Danish EPA
children; Europe; Personal care Danish Environmental Protection Agency Danish EPA
NOAEL Studies
Toxicology endpoints rendered from public NOAEL study rows.
SOURCE
NOAEL studies
Showing 28 of 28 studies
Value Unit Endpoint Route Species Source
=49 mg/m3 DNEL local inhalation Human ToxValDB_GESTIS_DNEL
=44.43 mg/m3 DNEL systemic inhalation Human ToxValDB_GESTIS_DNEL
KEH0A3F75J UNII FDA UNII substance identifier - - openFDA substances
KEH0A3F75J UNII FDA UNII substance identifier - - openFDA substances
KEH0A3F75J UNII FDA UNII substance identifier - - openFDA substances
KEH0A3F75J UNII FDA UNII substance identifier - - openFDA substances
- % Incidence of positive responses Dermal Human NTP_ICE_skin_sensitization
13500 ug/cm2 Induction dose per skin area Dermal Human NTP_ICE_skin_sensitization
>0.31 mg/L LC50 Inhalation - NTP_ICE_acute_inhalation
>2000 mg/kg bw LD50 oral Rat NTP_ICE_acute_oral
=3700 mg/kg bw LD50 oral Rat NTP_ICE_acute_oral
=4700 mg/kg bw LD50 oral Rat NTP_ICE_acute_oral
=4790 mg/kg bw LD50 oral Rat NTP_ICE_acute_oral
=800 mg/kg bw/day LEL oral Rat ToxValDB_ECHA_IUCLID
=1000 mg/kg bw/day LEL oral Rabbit ToxValDB_ECHA_IUCLID
=2000 mg/kg bw/day LEL oral Rat ToxValDB_EPA_TSCA_8e
=1000 mg/kg bw/day LOAEL oral Rat ToxValDB_ECHA_IUCLID
=1200 mg/kg bw/day LOEL oral Rat ToxValDB_EPA_TSCA_8e
=1600 mg/kg bw/day LOEL oral Rat ToxValDB_EPA_TSCA_8e
- unitless Model Score - - NTP_ICE_endocrine
=250 mg/kg bw/day NOAEL oral Rat ToxValDB_ECHA_IUCLID
=300 mg/kg bw/day NOAEL oral Rat ToxValDB_ECHA_IUCLID
=450 mg/kg bw/day NOAEL oral Rat ToxValDB_ECHA_IUCLID
=50 mg/kg bw/day NOEL oral Rat ToxValDB_ECHA_IUCLID
=200 mg/kg bw/day NOEL oral Rat ToxValDB_ECHA_IUCLID
=500 mg/kg bw/day NOEL oral Rat ToxValDB_ECHA_IUCLID
>=1000 mg/kg bw/day NOEL oral Rat ToxValDB_ECHA_IUCLID
3 unitless Relative reliability score Dermal Human NTP_ICE_skin_sensitization
Showing 28 of 28 studies
REACH Registration
Registration status from the ECHA REACH registered substances database.
SOURCE
ECHA (EU)
1 records
Status Name EC Number Link
Registered 2-methylpentane-2,4-diol 203-489-0 ECHA overview →
Australian Status (AICIS)
Australian industrial chemicals inventory status and applicable conditions.
SOURCE
AICIS inventory
1 records
Frequently Asked Questions
What is the GHS hazard classification for 2-Methyl-2,4-pentanediol?
2-Methyl-2,4-pentanediol (CAS 107-41-5) is classified under EU CLP Annex VI as Skin Irrit. 2; Eye Irrit. 2 with signal word Warning. Hazard statements: H315; H319. Source: EU CLP Annex VI (ECHA).
What is the NOAEL for 2-Methyl-2,4-pentanediol?
2-Methyl-2,4-pentanediol has 28 NOAEL studies in the database. The lowest reported value is 44.43 mg/m3 via inhalation in Human. Source: ToxValDB_GESTIS_DNEL.
What regulatory lists include 2-Methyl-2,4-pentanediol?
2-Methyl-2,4-pentanediol appears on 11 regulatory/inventory lists including Europe; Specialty occupational products, IFRA Transparency, SCIL (9/2019), and 8 more. Source: EPA CPDat.
What are the occupational exposure limits for 2-Methyl-2,4-pentanediol?
Occupational exposure limits for 2-Methyl-2,4-pentanediol are set by NIOSH, ACGIH, CAL/OSHA. 4 limit values from official agencies are documented in the database. Source: OSHA, NIOSH, ACGIH.
Is 2-Methyl-2,4-pentanediol used in cosmetics?
Yes, 2-Methyl-2,4-pentanediol is also indexed as a cosmetic ingredient under the name Hexylene Glycol. View the full cosmetic safety profile on the ingredient page for detailed safety data, SCCS opinions, and regulatory status.
Where does the safety data for 2-Methyl-2,4-pentanediol come from?
Safety data is sourced from ECHA CLP Annex VI, EPA ToxValDB, EPA CPDat, AICIS (Australian Industrial Chemicals Introduction Scheme), EPA DSSTox, ECHA REACH, ILO/WHO ICSC, OSHA/NIOSH/ACGIH, CosIng / Ingredients DB, ChEMBL / DailyMed. All data traces to primary regulatory sources and is updated from official government databases.
Is 2-Methyl-2,4-pentanediol used outside industrial chemicals?
2-Methyl-2,4-pentanediol also appears in cosmetics, pharmaceutical databases.